Pyrolysis
Pyrolysis
The thermal
decomposition of organic compounds is known as pyrolysis, when applied to
alkanes, is known as cracking.
When heated
to about 500-600oC, alkanes are decomposed into smaller molecules, and the
products obtained from a given alkane depend on (i) the structure of the
alkane; (ii) the pressure under which cracking is carried out; and (iii) the
presence or absence of catalysts such as silica-alumina, silica-alumina-thoria,
silica-alumina-zirconia.
The mechanism
of carking is still obscure. Many theories have been suggested, and one that is
highly favoured is a free-radical mechanism, evidence for which has been
obtained from the observation that at cracking temperatures many hydrocarbons
produce alkyl free radicals.
When
petroleum is cracked, of all the compounds produced, the most important are
those containing up to four carbons atoms : methane, ethane, ethylene, propane,
propene, butane, butane and isobutene. All of these have found wide application
as the materials for the preparation of a large number of chemicals.
By using
suitable catalysis, alkanes containing six or more carbon atoms may be
catalytically cyclised, e.g., n-hexane, under pressure, passed over
chromic oxide carried on an alumina support and heated at 480-550oC.
C6H14 - C6H6
+ 4H2
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