Carbon tetrachloride, CCl4
Carbon Tetrachloride, CCl4
Carbon tetrachloride is a colorless liquid, b.p. 77oC.
It has a sickly smell. It is insoluble in water but readily soluble in ethanol
and either. Since its vapour is non-inflammable.
Preparation of carbon Tetrachloride
Carbon tetrachloride is prepared industrially in several
ways:
(i) By the action of chlorine on carbon disulphide in the presence
of aluminum chloride as catalyst:
The sulphur monochloride is removed by fractional distillation,
and the carbon tetrachloride is then shaken with sodium hydroxide, and finally
distilled.
(ii) By the chlorination of methane
(iii) By chlorinolysis. This term describes the process of
chlorinating an organic compound under conditions which rupture the
carbon-carbon bond to yield chloro-compound with fewer carbon atoms than the
original compound. Chlorinolysis may be effected with or without a catalyst,
e.g., the hydrocarbon and chlorine are heated at high temperature (300-400oC)
and under high pressure (about 70 kg/cm2). The product is usually a mixture,
e.g., propane gives both carbon tetrachloride and hexachloroethane:
Carbon tetrachloride is stable at red heat (about 500oC),
but when its vapour comes into contract with water vapour at this temperature,
some carbonyl chloride is formed:
CCl4 + H2O → COCl2 + 2HCl
Hence after using pyrene to extinguish a fire, the room
should be well ventilated.
Use of Carbon Tetrachloride
Carbon tetrachloride is widely used as an industrial solvent
(for fats, oils, resins, lacquers, etc.). It is also used as a
fire-extinguisher under the name of Pyrene. Carbon tetrachloride
is reduced by moist iron filings to chloroform (q.v.). The alkaline hydrolysis
of carbon tetrachloride gives the same products (formate and carbon monoxide)
as chloroform, but the rate of reaction is slower.
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