Methanol
Methanol
Methanol or Methyl alcohol is also known as carbinol. Methanol
is a colorless, inflammable liquid, b.p. 64oC and is poisonous. It is
miscible with water in all proportions, and is also miscible with most organic
solvents. It burns with a faintly luminous flame, and its vapour forms
explosive mixtures with air or oxygen when ignited. It combines with calcium
chloride to form CaCl2.4CH3OH, and hence cannot be dried this
way (cf. ethanol).
Preparation of methanol (carbinol)
Methyl alcohol or methanol is prepared industrially by
several methods. The earliest method was the destructive distillation of wood,
whereby tar and an aqueous fraction known as pyroligneous acid are obtained. Pyroligneous
acid contains methanol, acetone and acetic acid, and all three compounds may be
obtained by suitable treatment. It was this method which gave rise to the name ‘wood
spirit’ for methanol. The modern methods are synthetic.
Synthesis gas is passed at a pressure of 200 atmospheres over
catalysts containing the oxides of copper, zinc and chromium at 300oC.
CO + 2H2 → CH3OH
If the proper precautions are taken, the yield of methanol
is almost 100 per cent, and its purity is above 99 per cent. By changing the
catalyst and the ratio of carbon monoxide to hydrogen, methanol and a variety
of higher alcohols are produced.
By the catalytic oxidation of methane. A mixture of methane
and oxygen (ratio by volume of 9:1) at a pressure of 100 atmospheres is passed
through a copper tube at 200oC:
Structure of Methanol
Analysis and molecular-weight determinations show that the
molecular formula of methanol is CH4O. Assuming that carbon is quadrivalent,
oxygen bivalent and hydrogen univalent, only the structure is possible:
This is supported by all the chemical reactions of methanol,
e.g., (i) only one hydrogen in methanol is replicable by sodium; this suggests
that one hydrogen atom is in a different state of combination from the other
three. (ii) Methanol is formed from methyl chloride by hydrolysis with sodium
hydroxide. Methyl chloride can have only the structure CH3Cl. It is
reasonable to suppose that the methyl group in methyl chloride is unchanged by
the action of dilute alkali, and that the reaction takes place by the replacement
of the chlorine atom by a hydroxyl group.
Use of Methanol
Methanol is used as a solvent for paints, varnishes,
shellac, celluloid cements, etc. in the manufacture of dyes, perfumes,
formaldehyde, etc. It is also used for making methylated spirit and automobile
antifreeze mixtures.
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